4-methylpentanoate
Key food odorantFound in 1 ingredient across the CompKitchen flavor graph.
Look up another compound — search by name, CAS number, PubChem CID, or FEMA #.
Key food odorant (intermediary)
Dunkel et al. 2014Identified in the meta-analysis of 227 food samples as one of 57 intermediary odorants — appears in 5–25% of foods. Characteristic odor: fruity, waxy.
Properties
- Odor description
- fruity, sweet, honey, apple, pear
- Odor threshold — orthonasal, in clean water
- 0.700 ppb – 147 ppb median 73.8 ppb · 2 published values · see all 17 with sources
- CAS number
- 106-32-1
FEMA GRAS — Generally Recognized As Safe for flavoring use
- FEMA number
- 4343
- GRAS publication
- GRAS 23
- FEMA primary name
- Ethyl 4-methylpentanoate
Reported use levels (ppm by food category)
Typical vs maximum reported addition levels in finished food. Use as a regulatory ceiling reference — verify against the current GRAS publication for your product category.
| Food category | Typical (ppm) | Maximum (ppm) |
|---|---|---|
| beverages (nonalcoholic) | 5 | 50 |
Published thresholds
17 measured values from the literature. Grouped by what was actually measured — a threshold smelled in clean water, tasted in the mouth, or measured in a real food are three different quantities and are not pooled.
Orthonasal, in clean water
0.700 ppb – 147 ppbThe reference measurement — smelled in water. OAV is computed against this.
| Threshold | Matrix | Source | Paper |
|---|---|---|---|
| 0.700 ppb SIDA | water | Rychlik 1998 · 1 studies | — |
| 147 ppb SIDA | water/ethanol 6:4 (food: american bourbon whisky) | Literature corpus | 30779560, 18570373, 15826061 +22 |
In a food matrix
1.9 ppb – 123 ppbMeasured in a real food, where the matrix shifts detection — not a clean-water value.
| Threshold | Matrix | Source | Paper |
|---|---|---|---|
| 0.022 ppb | water (food: beer) | Literature corpus | 17499755, 33889833 |
| Flagged: 191× from the median of this group. Excluded from the range above pending re-check against the source publication — shown rather than hidden. | |||
| 0.032 ppb | water (food: tea) | Literature corpus | 41551788 |
| Flagged: 132× from the median of this group. Excluded from the range above pending re-check against the source publication — shown rather than hidden. | |||
| 1.9 ppb SIDA | water (food: grape) | Literature corpus | 30779560, 18570373, 15826061 +22 |
| 2.0 ppb | water (food: rice) | Literature corpus | 26973621, 38846797, 40467248 +1 |
| 2.4 ppb | water (food: cheese) | Literature corpus | 42160145 |
| 3.5 ppb | water (food: orange) | Literature corpus | 37515910 |
| 5.0 ppb SIDA | water (food: apple) | Literature corpus | 30779560, 18570373, 15826061 +22 |
| 5.0 ppb SIDA | water (food: goat milk) | Literature corpus | 30779560, 18570373, 15826061 +22 |
| 76.0 ppb | water (food: wine) | Literature corpus | 25939071, 32657431, 41365581 |
| 108 ppb SIDA | water (food: unknown) | Literature corpus | 18570373, 25717332, 27664650 +2 |
| 123 ppb | water (food: lime) | Literature corpus | 15826061, 41048468 |
| 1196 ppb SIDA | water (food: bread) | Literature corpus | 18570373, 28274420, 28490062 +4 |
| Flagged: 283× from the median of this group. Excluded from the range above pending re-check against the source publication — shown rather than hidden. | |||
Retronasal / in-mouth
0.100 ppbTasted rather than smelled — a different sense, not comparable.
| Threshold | Matrix | Source | Paper |
|---|---|---|---|
| 0.100 ppb SIDA | water_retronasal | Rychlik 1998 · 1 studies | — |
Other matrix
4.5 ppb – 38.0 ppbMeasured in a non-aqueous medium (oil, starch, cellulose).
| Threshold | Matrix | Source | Paper |
|---|---|---|---|
| 4.5 ppb SIDA | wine matrix (12% ethanol) (food: red wine) | Literature corpus | 30779560, 18570373, 15826061 +22 |
| 38.0 ppb SIDA | starch | Rychlik 1998 · 1 studies | — |
Only values we can attribute are listed. Where a compendium's licence does not permit public attribution its figures are omitted here, so every number on this page traces to a citable source.
Where you'd actually smell it
Odor Activity Value = measured concentration ÷ odor threshold (3.46 ppb, the engine's canonical value — see the 17 published values). OAV ≥ 1 = perceptible.
| Food | Concentration (ppb) | OAV | Source |
|---|---|---|---|
| butter | 2000.0 | 578 ⚡ | Corpus paper |
| pineapple | 9.7 | 2.80 | PMID 30569201 |
Concentrations from PubMed Central Open Access papers (free literature corpus, MIT-style licensed). Copper = OAV ≥ 10 (strongly perceptible). Green = OAV ≥ 1 (perceptible).
Found in
Measured impact first, then profile shareEvery ingredient known to contain 4-methylpentanoate. Ingredients with a measured concentration come first, ranked by odour activity; the rest follow by how large a share of that ingredient's profile this molecule is. The figure beside each is how many different compounds that ingredient has in total — not the concentration of 4-methylpentanoate in it. Full concentrations are in the OAV table above.
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